Interfacial Engineering of Bi19Br3S27 Nanowires Promotes Metallic Photocatalytic CO2 Reduction Activity under Near-Infrared Light Irradiation.

Li, J; Pan, W; Liu, Q; Chen, Z; Chen, Z; Feng, X; Chen, H

Interfacial Engineering of Bi19Br3S27 Nanowires Promotes Metallic Photocatalytic CO2 Reduction Activity under Near-Infrared Light Irradiation.

Li, J Pan, W Liu, Q Chen, Z

Chen, Z

Feng, X Chen, H

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Publisher:: AMER CHEMICAL SOC
Publication Type:: Journal Article
Citation:: J Am Chem Soc, 2021, 143, (17), pp. 6551-6559
Issue Date:: 2021-05-05

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Field	Value	Language
dc.contributor.author	Li, J
dc.contributor.author	Pan, W
dc.contributor.author	Liu, Q
dc.contributor.author	Chen, Z https://orcid.org/0000-0003-0627-0856
dc.contributor.author	Chen, Z https://orcid.org/0000-0003-0627-0856
dc.contributor.author	Feng, X
dc.contributor.author	Chen, H
dc.date.accessioned	2022-05-06T05:47:46Z
dc.date.available	2022-05-06T05:47:46Z
dc.date.issued	2021-05-05
dc.identifier.citation	J Am Chem Soc, 2021, 143, (17), pp. 6551-6559
dc.identifier.issn	0002-7863
dc.identifier.issn	1520-5126
dc.identifier.uri	http://hdl.handle.net/10453/157090
dc.description.abstract	Developing highly efficient photocatalysts to utilize solar radiation for converting CO2 into solar fuels is of great importance for energy sustainability and carbon neutralization. Herein, through an alkali-etching-introduced interface reconstruction strategy, a nanowire photocatalyst denoted as V-Bi19Br3S27, with rich Br and S dual-vacancies and surface Bi-O bonding introduced significant near-infrared (NIR) light response, has been developed. The as-obtained V-Bi19Br3S27 nanowires exhibit a highly efficient metallic photocatalytic reduction property for converting CO2 into CH3OH when excited solely under NIR light irradiation. Free of any cocatalyst and sacrificial agent, metallic defective V-Bi19Br3S27 shows 2.3-fold higher CH3OH generation than Bi19Br3S27 nanowires. The detailed interfacial structure evolution and reaction mechanism have been carefully illustrated down to the atomic scale. This work provides a unique interfacial engineering strategy for developing high-performance sulfur-based NIR photocatalysts for photon reducing CO2 into alcohol for achieving high-value solar fuel chemicals, which paves the way for efficiently using the solar radiation energy extending to the NIR range to achieve the carbon neutralization goal.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	AMER CHEMICAL SOC
dc.relation.ispartof	J Am Chem Soc
dc.relation.isbasedon	10.1021/jacs.1c01109
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.title	Interfacial Engineering of Bi19Br3S27 Nanowires Promotes Metallic Photocatalytic CO2 Reduction Activity under Near-Infrared Light Irradiation.
dc.type	Journal Article
utslib.citation.volume	143
utslib.location.activity	United States
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
utslib.copyright.status	closed_access	*
dc.date.updated	2022-05-06T05:47:44Z
pubs.issue	17
pubs.publication-status	Published
pubs.volume	143
utslib.citation.issue	17

Abstract:

Developing highly efficient photocatalysts to utilize solar radiation for converting CO2 into solar fuels is of great importance for energy sustainability and carbon neutralization. Herein, through an alkali-etching-introduced interface reconstruction strategy, a nanowire photocatalyst denoted as V-Bi19Br3S27, with rich Br and S dual-vacancies and surface Bi-O bonding introduced significant near-infrared (NIR) light response, has been developed. The as-obtained V-Bi19Br3S27 nanowires exhibit a highly efficient metallic photocatalytic reduction property for converting CO2 into CH3OH when excited solely under NIR light irradiation. Free of any cocatalyst and sacrificial agent, metallic defective V-Bi19Br3S27 shows 2.3-fold higher CH3OH generation than Bi19Br3S27 nanowires. The detailed interfacial structure evolution and reaction mechanism have been carefully illustrated down to the atomic scale. This work provides a unique interfacial engineering strategy for developing high-performance sulfur-based NIR photocatalysts for photon reducing CO2 into alcohol for achieving high-value solar fuel chemicals, which paves the way for efficiently using the solar radiation energy extending to the NIR range to achieve the carbon neutralization goal.

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http://hdl.handle.net/10453/157090