Facile synthesis of black phosphorene via a low melting media assisted ball milling

Zhou, F; Li, S; Ouyang, L; Liu, J; Liu, J; Huang, Z; Zhu, M

Facile synthesis of black phosphorene via a low melting media assisted ball milling

Zhou, F Li, S Ouyang, L Liu, J Liu, J Huang, Z

Zhu, M

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Publisher:: Elsevier BV
Publication Type:: Journal Article
Citation:: Chemical Engineering Journal, 2022, 444, pp. 136593
Issue Date:: 2022-09-15

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Field	Value	Language
dc.contributor.author	Zhou, F
dc.contributor.author	Li, S
dc.contributor.author	Ouyang, L
dc.contributor.author	Liu, J
dc.contributor.author	Liu, J
dc.contributor.author	Huang, Z https://orcid.org/0000-0003-1985-0884
dc.contributor.author	Zhu, M
dc.date.accessioned	2022-08-02T10:32:11Z
dc.date.available	2022-08-02T10:32:11Z
dc.date.issued	2022-09-15
dc.identifier.citation	Chemical Engineering Journal, 2022, 444, pp. 136593
dc.identifier.issn	1385-8947
dc.identifier.uri	http://hdl.handle.net/10453/159495
dc.description.abstract	Few-layer phosphorene (FLP) has attracted strong research interest due to its extraordinary physical and chemical properties. However, an efficient and rapid fabrication of high-quality FLP is still unavailable. Herein, a simple and efficient low melting media-assisted ball milling (LMMBM) approach is developed to prepare FLP in large quantities. The phase change of the LMM at higher temperatures leads to FLP with larger lateral dimensions compared to the ones obtained via dry solid state ball milling. Transmission electron microscope (TEM) studies indicated that liquid facilitates the slipping/curling of black phosphorus (BP) layers under the shearing force generated during ball milling. When used as an anode in Lithium-ion batteries, the FLP-C composite exhibits high initial Coulombic efficiency, stable cycling and rate capacity. This LMMBM approach can be adopted for mass production of other two-dimensional materials from their bulk counterparts.
dc.language	en
dc.publisher	Elsevier BV
dc.relation	http://purl.org/au-research/grants/arc/FT190100658
dc.relation.ispartof	Chemical Engineering Journal
dc.relation.isbasedon	10.1016/j.cej.2022.136593
dc.rights	info:eu-repo/semantics/embargoedAccess
dc.subject	0904 Chemical Engineering, 0905 Civil Engineering, 0907 Environmental Engineering
dc.subject.classification	Chemical Engineering
dc.title	Facile synthesis of black phosphorene via a low melting media assisted ball milling
dc.type	Journal Article
utslib.citation.volume	444
utslib.for	0904 Chemical Engineering
utslib.for	0905 Civil Engineering
utslib.for	0907 Environmental Engineering
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
utslib.copyright.status	open_access	*
utslib.copyright.embargo	2024-04-01T00:00:00+1000Z
dc.date.updated	2022-08-02T10:32:07Z
pubs.publication-status	Accepted
pubs.volume	444

Abstract:

Few-layer phosphorene (FLP) has attracted strong research interest due to its extraordinary physical and chemical properties. However, an efficient and rapid fabrication of high-quality FLP is still unavailable. Herein, a simple and efficient low melting media-assisted ball milling (LMMBM) approach is developed to prepare FLP in large quantities. The phase change of the LMM at higher temperatures leads to FLP with larger lateral dimensions compared to the ones obtained via dry solid state ball milling. Transmission electron microscope (TEM) studies indicated that liquid facilitates the slipping/curling of black phosphorus (BP) layers under the shearing force generated during ball milling. When used as an anode in Lithium-ion batteries, the FLP-C composite exhibits high initial Coulombic efficiency, stable cycling and rate capacity. This LMMBM approach can be adopted for mass production of other two-dimensional materials from their bulk counterparts.

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http://hdl.handle.net/10453/159495