Introducing Stacking Faults into Three-Dimensional Branched Nickel Nanoparticles for Improved Catalytic Activity.

Ramadhan, ZR; Poerwoprajitno, AR; Cheong, S; Webster, RF; Kumar, PV; Cychy, S; Gloag, L; Benedetti, TM; Marjo, CE; Muhler, M; Wang, D-W; Gooding, JJ; Schuhmann, W; Tilley, RD

Introducing Stacking Faults into Three-Dimensional Branched Nickel Nanoparticles for Improved Catalytic Activity.

Ramadhan, ZR Poerwoprajitno, AR Cheong, S Webster, RF Kumar, PV Cychy, S Gloag, L

Benedetti, TM Marjo, CE Muhler, M Wang, D-W Gooding, JJ Schuhmann, W Tilley, RD

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Publisher:: American Chemical Society (ACS)
Publication Type:: Journal Article
Citation:: J Am Chem Soc, 2022, 144, (25), pp. 11094-11098
Issue Date:: 2022-06-29

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Field	Value	Language
dc.contributor.author	Ramadhan, ZR
dc.contributor.author	Poerwoprajitno, AR
dc.contributor.author	Cheong, S
dc.contributor.author	Webster, RF
dc.contributor.author	Kumar, PV
dc.contributor.author	Cychy, S
dc.contributor.author	Gloag, L https://orcid.org/0000-0001-7548-1521
dc.contributor.author	Benedetti, TM
dc.contributor.author	Marjo, CE
dc.contributor.author	Muhler, M
dc.contributor.author	Wang, D-W
dc.contributor.author	Gooding, JJ
dc.contributor.author	Schuhmann, W
dc.contributor.author	Tilley, RD
dc.date.accessioned	2023-04-04T01:27:44Z
dc.date.available	2023-04-04T01:27:44Z
dc.date.issued	2022-06-29
dc.identifier.citation	J Am Chem Soc, 2022, 144, (25), pp. 11094-11098
dc.identifier.issn	0002-7863
dc.identifier.issn	1520-5126
dc.identifier.uri	http://hdl.handle.net/10453/169097
dc.description.abstract	Creating high surface area nanocatalysts that contain stacking faults is a promising strategy to improve catalytic activity. Stacking faults can tune the reactivity of the active sites, leading to improved catalytic performance. The formation of branched metal nanoparticles with control of the stacking fault density is synthetically challenging. In this work, we demonstrate that varying the branch width by altering the size of the seed that the branch grows off is an effective method to precisely tune the stacking fault density in branched Ni nanoparticles. A high density of stacking faults across the Ni branches was found to lower the energy barrier for Ni2+/Ni3+ oxidation and result in enhanced activity for electrocatalytic oxidation of 5-hydroxylmethylfurfural. These results show the ability to synthetically control the stacking fault density in branched nanoparticles as a basis for enhanced catalytic activity.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	American Chemical Society (ACS)
dc.relation.ispartof	J Am Chem Soc
dc.relation.isbasedon	10.1021/jacs.2c04911
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.subject.mesh	Catalysis
dc.subject.mesh	Metal Nanoparticles
dc.subject.mesh	Nickel
dc.subject.mesh	Nickel
dc.subject.mesh	Catalysis
dc.subject.mesh	Metal Nanoparticles
dc.subject.mesh	Catalysis
dc.subject.mesh	Metal Nanoparticles
dc.subject.mesh	Nickel
dc.title	Introducing Stacking Faults into Three-Dimensional Branched Nickel Nanoparticles for Improved Catalytic Activity.
dc.type	Journal Article
utslib.citation.volume	144
utslib.location.activity	United States
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
utslib.copyright.status	closed_access	*
dc.date.updated	2023-04-04T01:27:42Z
pubs.issue	25
pubs.publication-status	Published
pubs.volume	144
utslib.citation.issue	25

Abstract:

Creating high surface area nanocatalysts that contain stacking faults is a promising strategy to improve catalytic activity. Stacking faults can tune the reactivity of the active sites, leading to improved catalytic performance. The formation of branched metal nanoparticles with control of the stacking fault density is synthetically challenging. In this work, we demonstrate that varying the branch width by altering the size of the seed that the branch grows off is an effective method to precisely tune the stacking fault density in branched Ni nanoparticles. A high density of stacking faults across the Ni branches was found to lower the energy barrier for Ni2+/Ni3+ oxidation and result in enhanced activity for electrocatalytic oxidation of 5-hydroxylmethylfurfural. These results show the ability to synthetically control the stacking fault density in branched nanoparticles as a basis for enhanced catalytic activity.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/169097