Transport tuning strategies in MOF film synthesis - a perspective

Zulkifli, MYB; Lin, R; Chai, M; Chen, V; Hou, J

Transport tuning strategies in MOF film synthesis - a perspective

Zulkifli, MYB Lin, R Chai, M Chen, V

Hou, J

Permalink

Publisher:: Royal Society of Chemistry (RSC)
Publication Type:: Journal Article
Citation:: Journal of Materials Chemistry A, 2022, 10, (28), pp. 14641-14654
Issue Date:: 2022-06-07

Closed Access

	Filename	Description	Size
	d2ta03216c.pdf	Published version	1.2 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Zulkifli, MYB
dc.contributor.author	Lin, R
dc.contributor.author	Chai, M
dc.contributor.author	Chen, V https://orcid.org/0000-0002-6604-6197
dc.contributor.author	Hou, J
dc.date.accessioned	2023-07-17T02:05:08Z
dc.date.available	2023-07-17T02:05:08Z
dc.date.issued	2022-06-07
dc.identifier.citation	Journal of Materials Chemistry A, 2022, 10, (28), pp. 14641-14654
dc.identifier.issn	2050-7488
dc.identifier.issn	2050-7496
dc.identifier.uri	http://hdl.handle.net/10453/171537
dc.description.abstract	Metal-organic frameworks (MOFs), sometimes also known as coordination polymers, are a very versatile group of materials consisting of metal nodes and organic linkers forming a tunable porous structure that can exist in different structural phases. The capability to synthesise MOF films allows for application in many different fields such as separation, energy, and catalysis. This perspective aims to explore the transport mechanism and tuning strategies in different types of MOF thin films tailored for different applications. Intracrystalline transport, which has been widely studied, has been shown to successfully aid in the selective transport of different molecules by adjusting the MOF's pore structure and environment. However, in the context of thin film, it is also important to consider interframework (for mixed matrix membrane (MMM) thin film) or intercrystalline (for polycrystalline thin film) based transport as it also directly impacts the overall transport of the thin film. Here we highlight the current intracrystalline and intercrystalline/interframework transport tuning strategies, as well as chart a course for future transport tuning strategies tailored for current and future applications.
dc.language	en
dc.publisher	Royal Society of Chemistry (RSC)
dc.relation	http://purl.org/au-research/grants/arc/DP180103874
dc.relation.ispartof	Journal of Materials Chemistry A
dc.relation.isbasedon	10.1039/d2ta03216c
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0303 Macromolecular and Materials Chemistry, 0912 Materials Engineering, 0915 Interdisciplinary Engineering
dc.subject.classification	3403 Macromolecular and materials chemistry
dc.subject.classification	4004 Chemical engineering
dc.subject.classification	4016 Materials engineering
dc.title	Transport tuning strategies in MOF film synthesis - a perspective
dc.type	Journal Article
utslib.citation.volume	10
utslib.for	0303 Macromolecular and Materials Chemistry
utslib.for	0912 Materials Engineering
utslib.for	0915 Interdisciplinary Engineering
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Provost
utslib.copyright.status	closed_access	*
dc.date.updated	2023-07-17T02:05:07Z
pubs.issue	28
pubs.publication-status	Published
pubs.volume	10
utslib.citation.issue	28

Abstract:

Metal-organic frameworks (MOFs), sometimes also known as coordination polymers, are a very versatile group of materials consisting of metal nodes and organic linkers forming a tunable porous structure that can exist in different structural phases. The capability to synthesise MOF films allows for application in many different fields such as separation, energy, and catalysis. This perspective aims to explore the transport mechanism and tuning strategies in different types of MOF thin films tailored for different applications. Intracrystalline transport, which has been widely studied, has been shown to successfully aid in the selective transport of different molecules by adjusting the MOF's pore structure and environment. However, in the context of thin film, it is also important to consider interframework (for mixed matrix membrane (MMM) thin film) or intercrystalline (for polycrystalline thin film) based transport as it also directly impacts the overall transport of the thin film. Here we highlight the current intracrystalline and intercrystalline/interframework transport tuning strategies, as well as chart a course for future transport tuning strategies tailored for current and future applications.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/171537