Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries

Liu, Q; Yu, L; Wang, Y; Ji, Y; Horvat, J; Cheng, ML; Jia, X; Wang, G

Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries

Liu, Q Yu, L Wang, Y

Ji, Y Horvat, J Cheng, ML Jia, X Wang, G

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Publication Type:: Journal Article
Citation:: Inorganic Chemistry, 2013, 52 (6), pp. 2817 - 2822
Issue Date:: 2013-03-18

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Field	Value	Language
dc.contributor.author	Liu, Q	en_US
dc.contributor.author	Yu, L	en_US
dc.contributor.author	Wang, Y https://orcid.org/0000-0002-0290-0112	en_US
dc.contributor.author	Ji, Y	en_US
dc.contributor.author	Horvat, J	en_US
dc.contributor.author	Cheng, ML	en_US
dc.contributor.author	Jia, X	en_US
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578	en_US
dc.date.issued	2013-03-18	en_US
dc.identifier.citation	Inorganic Chemistry, 2013, 52 (6), pp. 2817 - 2822	en_US
dc.identifier.issn	0020-1669	en_US
dc.identifier.uri	http://hdl.handle.net/10453/26324
dc.description.abstract	Manganese-based layered coordination polymer ([Mn(tfbdc)(4,4′-bpy) (H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H 2tfbdc) and 4,4′-bipyridine(4,4′-bpy) with manganese(II) acetate tetrahydrate in water solution. Mn-LCP was characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray single-crystal structure analysis, and powder X-ray diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between Mn(II) ions in Mn-LCP. As anode material, the Mn-LCP electrode exhibits an irreversible high capacity in the first discharge process and a reversible lithium storage capacity of up to about 390 mA h/g from the fourth cycle. It might provide a new method for finding new electrode materials in lithium-ion batteries © 2013 American Chemical Society.	en_US
dc.relation.ispartof	Inorganic Chemistry	en_US
dc.relation.isbasedon	10.1021/ic301579g	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries	en_US
dc.type	Journal Article
utslib.citation.volume	6	en_US
utslib.citation.volume	52	en_US
utslib.for	0399 Other Chemical Sciences	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0302 Inorganic Chemistry	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	6	en_US
pubs.publication-status	Published	en_US
pubs.volume	52	en_US

Abstract:

Manganese-based layered coordination polymer ([Mn(tfbdc)(4,4′-bpy) (H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H 2tfbdc) and 4,4′-bipyridine(4,4′-bpy) with manganese(II) acetate tetrahydrate in water solution. Mn-LCP was characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray single-crystal structure analysis, and powder X-ray diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between Mn(II) ions in Mn-LCP. As anode material, the Mn-LCP electrode exhibits an irreversible high capacity in the first discharge process and a reversible lithium storage capacity of up to about 390 mA h/g from the fourth cycle. It might provide a new method for finding new electrode materials in lithium-ion batteries © 2013 American Chemical Society.

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http://hdl.handle.net/10453/26324