Atmospheric Water Harvesting with Polymeric Hydrogels

Publication Type:
Thesis
Issue Date:
2025
Full metadata record
Water scarcity remains a pressing global challenge despite the abundance of Earth's water resources, necessitating innovative and sustainable water extraction technologies. Conventional methods, such as desalination and river diversion, are economically and environmentally unsustainable, prompting interest in atmospheric water harvesting (AWH) using chemical adsorption materials. This thesis explores hydrogel-based AWH materials, focusing on their structural properties, adsorption and desorption thermodynamics, and biomimetic design. The research examines the influence of polymer network characteristics, including crosslink density and functional groups, on adsorption kinetics, while also analyzing macroscopic factors such as pore size, density, and wall thickness. The desorption process in hydrogels is found to be thermodynamically distinct, requiring higher energy due to the strong hydrogen bonding network. Experimental findings demonstrate that double-layered composite hydrogels exhibit a 58.71% increase in water adsorption capacity compared to single-layered counterparts, underscoring the efficacy of independent functional components. Furthermore, the addition of salt components with unique approaches and customized morphology, along with their successful integration into an AWH device, confirms the material’s potential for practical implementation. These findings contribute to the advancement of cost-effective, scalable, and sustainable AWH technologies, addressing the critical issue of freshwater scarcity and supporting global water security initiatives.
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